the aqua complex [Co(NH3)5OH2]3+, formed as an intermediate, reacts with a nitrite buffer [details are in R.G. Pearson,P.M. Henry, J.G. Bergmann and F. Basolo, J. Am. Chem. Soc., 76, 5920, (1954)]. This reaction is interesting because it is a good example of an intramolecular rearrangement (see R.K Murmann and H. Taube, J. Am. Chem. Soc., 78, 4886, (1954)). It is also possible to reverse this reaction (κN to κO) using UV light. In these two isomers the ligand possesses different steric requirements…
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