Open system and multicomponent - Single phase at T and P - Variable composition (n1, n2, n3 etc) So Gibbs energy (G) could be written as a function of T, P, n1, n2, n3 etc. (nG) = g ( P,T , n1 , n2 ....ni ) Apply partial differentiation and FPR (Chapter 6), ( ) ⎤⎥ ⎡ ∂ nG d nG = ⎢ ⎢⎣ ∂ P ( ) ( ) ⎤⎥ ⎡ ∂ nG dP + ⎢ ⎥⎦T ,n ⎢⎣ ∂T ( ) ⎤⎥ ⎡ ∂ nG dT + ∑ ⎢ i ⎢ ∂ ni ⎥⎦ P,n ⎣ ( ) ⎤⎥ ⎡ ∂ nG d nG = nVdP − nSdT + ∑ ⎢ i ⎢ ⎣ ∂ ni ( ) Let's define ( ) ⎤⎥ ⎡ ∂ nG µi = ⎢ ⎢⎣ ∂ ni ⎥⎦ P,T ,n j ⎥⎦ P,T ,n j…
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